Hi Key Steps to Improving the Customer Experience through Business Process Management (BPM).

Hi Key Steps to Improving the Customer Experience through Business Process Management (BPM).

*Competing effectively in today's business world means 

considering broader customer experience issues:

Business Process Management (BPM) is the foundational ingredient you’ll need to bring everything together across brands, venues and channels to deliver a seamless customer experience. Effective BPM combines process improvement techniques with business process automation technology to create ‘systems of co-ordination’ that manage and improve knowledge about ‘what works in work’; and apply this knowledge to directly co-ordinate and measure work in day-to-day business operations.

This whitepaper explores how you can use BPM to deliver a consistency and continuity of service across all customer experience channels and makes it easy for customers to work with you.

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Hi Whitepaper Trio Download! Belts.., Drives & * More...,

Hi Whitepaper Trio Download! Belts.., Drives & * More...,

Hi Energy Savings from Synchronous Belts;

Synchronous belt drives operate so efficiently that they enable up to 5% energy savings, while also reducing maintenance and downtime across applications. Read this Gates paper for a comparison of V-belts and synchronous belts, to learn how to calculate potential energy savings, and to estimate the payback period after a drive conversion. Plus, you’ll see how one global manufacturer achieved savings of over $34,000 with synchronous belt drives.

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Hi Designing Drives for a Competitive Edge;

If you’re an electromechanical engineer who designs power transmission or motion control systems for industrial equipment, you face a challenge. You must adopt new technologies to remain competitive. Download this Gates paper to learn how a field redesign can save on costs, improve productivity, and reduce downtime and maintenance. It also includes two field retrofit case studies that show how forward-thinking facilities implemented new drive designs for improved performance and impressive savings.

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Hi How Belt Drives Impact Overhung Load;

Today’s belt drive systems are capable of transmitting enormous power in a compact space. What impact does this load-carrying capacity have on the shafts and bearings of speed reducers attached to belt drives? The answer lies in understanding Overhung Load (OHL). Read this Gates paper for practical guidelines that will help you determine whether your drive has exceeded the maximum OHL value.

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THANK YOU FOR DOWNLOADING Hi WHITEPAPERS!. 

Hi Dual Core Whitepaper Download!. Discussing the most pressing issues and innovative solutions in the industry!.

Hi Dual Core Whitepaper Download!. Discussing the most pressing issues and innovative solutions in the industry!.

Mersen Pioneers Safety and Reliability Solutions for Hydro Generators:

Mersen;

Hydro power plants drive electric generators which produce high-voltage AC power for the grid. These generators consist of two main components, a wound rotor (rotating part) driven by...

Vital Cooling Tubes for CERN's Large Hadron Collider:

Fine Tubes;

Particle physics does not usually hit world headlines. But in July 2012, physicists at CERN, the European Organization for Nuclear Research near Geneva, achieved what could be billed as...

Hi The Fall 2014 GRIT Report Is Here!

Hi The Fall 2014 GRIT Report Is Here!

The 15th edition of the GreenBook Research Industry Trends Report is here! The report contains nearly 80 pages of the most recent trends data, incisive analysis and thoughtful commentary on the state of the market research industry and where we are heading in the future.

Click Image Above To Download Industry Trends Guide!!!. 

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Hi Learn how to select the right data logger.

Hi Learn how to select the right data logger.

Hi Magazine! Environmental Design + Construction Hi Final Edition!

Hi Magazine! Environmental Design + Construction Hi Final Edition!

Welcome to the final issue of edc!!!

Hi Click Link Here For Direct Link To Download Or View Below; Hi Latest & Final Edition!.

Hi View This Issue;

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Hi Automatic Identification of Pallets:

Hi Automatic Identification of Pallets:

Cognex has developed an application dedicated to the automatic reading of barcodes on pallets. 

The advantages of imaging technology combined with the capabilities of the DataMan® range of barcode readers offer a high-performance and competitive solution for this application.

Scan one or multiple codes on any pallet indoor or outdoor, even if the codes are damaged, scratched, folded or covered with a film, and achieve the highest read rates on the market no matter if the reader is fixed on the wall, on a conveyor or even directly placed on a forklift. 

Hi Track Customer Experience, but Don’t Forget the Financials!.

Hi Track Customer Experience, but Don’t Forget the Financials!.

Businesses are always on the hunt for customer feedback. They e-mail us surveys. They ask us to stay on the phone after a service call to rate the interaction. Many rely on metrics such as the Net Promoter Score to track how customers feel about them. The most disciplined firms not only exploit the data to identify problems with their products and services but also get everyone on staff involved in fixing them.

This “customer experience” movement, if we can call it that, reminds me of the period a couple of decades ago when manufacturers (and others) discovered quality. Remember quality circles? Total Quality Management? Company after company learned to use new metrics and to address the root causes of problems. Front-line employees began monitoring their own output and figuring out improvements.

It’s worth recalling this push for better quality, because we wouldn’t want to repeat an unfortunate aspect of it. People got so caught up in trying to improve quality they sometimes forgot that a business has to make money, too. The Wallace Company, an oilfield-supply company, famously won the Malcolm Baldrige National Quality Award in 1990 and filed for bankruptcy shortly thereafter. Many other firms embarked on ambitious quality programs only to scale them back later on because they proved to be too expensive.

So far, no business I’m aware of has Net Promotered itself into insolvency. But look at things from the perspective of the front-line employee who is being asked to take responsibility for keeping customers happy. Should I schedule yet another service visit? What about forgiving this bounced-check fee? Should I honor that warranty even though it expired a month ago? These are difficult decisions; they require tradeoffs between customer delight on the one hand and costs on the other.

So here’s an idea: Let’s have employees monitor customer feedback and make improvements in response to it while also watching key financial indicators and taking actions to move them in the right direction. Every executive knows — or should know — that good business decisions require both kinds of input. If companies are going to ask front-line employees to make more decisions themselves, the front-liners will need to know how to keep customers happy andwhat it costs to do so.

How to combine the two sensibilities? Imagine a daily or weekly dashboard showing relevant customer-feedback scores and comments, along with key financial numbers—variance to budget, cost per customer, whatever the most important figures might be. Employees will quickly learn to track the short-term tradeoffs and will naturally try to keep costs under control. But they’ll also be curious to know about the longer-term benefits. If they schedule a lot of extra service visits, for example, or regularly honor those expired warrantees, the cost of service will rise. But there’s likely to be a payoff in greater customer loyalty — meaning less churn and reduced customer-acquisition costs.

Front-line employees don’t need to become statisticians. The folks in finance can perform the analyses that show them which tradeoffs are worth making and why. But now the front-liners will be thinking like businesspeople, understanding from the data when they can afford to give the customer an extra benefit and when they can’t. Their decisions will be that much better, and the company won’t go broke trying to satisfy every customer’s wish, at any cost.

Hi Chemical Engineer! Digital Magazine!.

Hi Chemical Engineer! Digital Magazine!.

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Hi Featured Report! Commodity Price Volatility - What Goes Up, Must Come Down!!

Hi Featured Report! Commodity Price Volatility - What Goes Up, Must Come Down!!

Volatility, a measurement of how much something changes over time, has plagued commodity markets in recent years. 

Rapid price adjustments and re-adjustments have reduced most purchasing plans to shreds. 

This has made it more difficult for buyers to time purchases, effectively execute market plans and gain a better perspective of the future. 

A rising factor in supply chains has been the deeper and faster penetration of upstream costs into downstream products. 

Further speculation has now become much more prominent further influencing commodity price swings. 

How will this, key input costs and market demand influence tomorrow’s price? This whitepaper will help you understand the characteristics of recent periods of volatility and provides valuable guidance in how to face volatile times to come.

*Download the IHS whitepapers listed below and obtain cost insight and answers to your questions, including:

• How will inflation affect my production costs?
• What’s the best way to anticipate price change?
• How will key input costs, and market demand influence tomorrow’s price?
• What risks do commodity prices pose directly to my costs?

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Further Reading Whitepaper Download!!!>

A. Pricing Risks – Be Prepared for the Next Round of Commodity Price Swings. Click Here!!!

&

B. How Will Inflation Affect Your Production Costs? Click Here!!!

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Hi Application note: pumping fluids in hazardous environments.

Hi Application note: pumping fluids in hazardous environments.

‘Pumping fluids in hazardous environments’

For more than 15 years, Verder has manufactured and distributed air-operated diaphragm pumps. During this time, the company has looked for ways of improving the design. Today, Verder manufactures its own best-in-class diaphragm pump, explains Wim Rochtus, product manager for Verderair pumps at Verder International.

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Hi Corporate Responsibility: Operating in the Green!.

Hi Corporate Responsibility: Operating in the Green!.

SPONSORED BY; 

Within the material handling industry, there are numerous opportunities to positively impact our environment: improving air quality, reducing energy consumption, reducing waste, increasing recycling and increasing safety. 

This complimentary white paper will describe the importance of achieving sustainability through efficiency and waste reduction, and how it contributes to productivity in operations. 

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Hi Mercedes F1 power unit honoured as outstanding example of British engineering!.

Hi Mercedes F1 power unit honoured as outstanding example of British engineering!.

The team behind the power unit at the heart of Mercedes’

recent Formula One success has been awarded the 2014

Dewar Trophy for outstanding British technical 

achievement in the automotive industry.

Developed by Mercedes AMG High Performance Powertrains (HPP) at Brixworth in Northamptonshire, the PU106A Hybrid power unit has been the dominant powertrain in the first season under new F1 rules, which have replaced the 2.4-litre normally-aspirated V8 engines with 1.6 litre charged V6 power unit that relies heavily on hybrid technologies.

The Mercedes-Benz PU106A Hybrid power unit.

Top flight motorsport has faced mounting criticism in recent years that it is not longer relevant to the wider automotive industry. It’s hoped that the new regulations - which align performance more closely with thermal efficiency - could have direct relevance to future the road car power-trains.

With a claimed thermal efficiency of more than 40 per cent the Mercedes is said to be the most thermally efficient gasoline powertrain ever produced and has been a key factor in helping Mercedes AMG Petronas secure the 2014 FIA Formula One Constructors’ Championship.

Previous winners of the Dewar Trophy  - which is organised by the Royal Automobile Club - have included Rolls-Royce in 1907 for its 40.5hp engine; Dunlop in 1957 for work developing disc brakes and modern tyres; the British Motor Corporation and Alec Issigonis for the original Mini in 1959; Jaguar in 2003 for its all-aluminium chassis; and Ford for its EcoBoost drivetrain in 2012.

Awarding the 2014 trophy to HPP was a unanimous decision made by experts on the Dewar Technical Committee, chaired by John Wood MBE.

Hi Egypt, Arab Republic of - EGYPT Energy/Social Safety Nets Sector Reforms Technical Assistance : P144305 - Implementation Status Results Report : Sequence 02 (English):

Hi Egypt, Arab Republic of - EGYPT Energy/Social Safety Nets Sector Reforms Technical Assistance : P144305 - Implementation Status Results Report : Sequence 02 (English):

Egypt, Arab Republic of;

Hi COMPLETE REPORT IN ENGLISH Official version of document:

Hi Click The Direct Following Link Here To Start Download.

Hi At My Brainy; Plasmon-assisted radiolytic energy conversion in aqueous solutions.

Hi At My Brainy; Plasmon-assisted radiolytic energy conversion in aqueous solutions.

The field of conventional energy conversion using radioisotopes has almost exclusively focused on solid-state materials. Herein, we demonstrate that liquids can be an excellent media for effective energy conversion from radioisotopes. We also show that free radicals in liquid, which are continuously generated by beta radiation, can be utilized for electrical energy generation. Under beta radiation, surface plasmon obtained by the metallic nanoporous structures on TiO2 enhanced the radiolytic conversion via the efficient energy transfer between plasmons and free radicals. This work introduces a new route for the development of next-generation power sources.

Hi - At a glance;

Hi - Introduction:

Particles emitted from radioisotopes can be used to convert the radiant energy into electricity. Radioisotope energy conversion for power generation has been intensively studied to develop power sources for wide range of applications, from energizing cardiac pacemakers in human body to challenging outer planet missions. As compared to various indirect conversion methods, which collect electricity from the secondary energy forms of heat or light generated by radiation, direct conversion methods produce electric power straight from energetic particles. Beta particles can produce electron-hole pairs in semiconductors via their loss of kinetic energy and can contribute to the generation of electric power. Although potential applicability of radioisotopes in portable power sources that do not require recharging seems very attractive, it has been reported that only a small portion of the entire radiation energy can be converted into electrical energy. Moreover, most betavoltaic cells suffer from serious radiation damage to the lattice structures of semiconductors and subsequent performance degradation due to the high kinetic energy of the beta particles. Alternatively, to minimise lattice damage in semiconductors, wide band gap materials are typically used. However, radiation-resistive materials, such as SiC and GaN, still show very low energy conversion efficiencies. Little improvement has been made even after vigorous research on various improvement methods utilizing porous structures, inverted pyramidal cavities, and three dimensional silicon pillar structures to increase rectifying junction areas. Although, thus far, there is no method for completely avoiding radiation damage to semiconductors, the use of a liquid-phase semiconductor material has been introduced as a possible means to overcome the radiation damage and structural defect problem. One major benefit of utilising a liquid-phase material is the well-known ability to efficiently absorb the kinetic energy of beta particles.

Since the advent of nuclear power, liquids have been intensively studied for use as a radiation-shielding material. Large amounts of radiation energy can be absorbed by water. When radiation energy is absorbed by an aqueous solution, free radicals (e.g., eaq⁻, ^·OH, H^·, HO2^·) can be produced through radiolytic interactions. These free radicals are known to affect the generation of molecular by-products, such as H2O2 and H2. However, counterintuitively, the generation of electricity from a solution containing an ample amount of absorbed radiation energy has not yet been vigorously studied. Here, we demonstrate a new method for the generation of electricity using a device that separates the radiolytic current from the free radicals by splitting the water.

Hi - Design and operating principle of Pt/nanoporous 

TiO2 radiolytic cell:

Our water splitter is composed of a nanoporous semiconductor coated with a thin Pt film to produce a specially designed metal-semiconductor junction. As a suitable semiconductor material for water decomposition, we used a very stable and common large band gap oxide material, TiO2, because the use of large band gap oxide materials as a semiconducting catalyst can improve the radiolysis yield. Nanoporous TiO2 was formed by anodising and subsequently thermally oxidising a thin Ti film. The large surface area of the porous structure can provide more chemical reaction sites than a planar surface. To form a stable Schottky contact at the semiconductor/metal interface, a thin Pt film was uniformly deposited using a radio frequency (RF) sputtering system. As shown in the band diagram of the junctions, a Schottky barrier of 0.45 eV is formed because the Fermi energy (EF) of TiO2, an n-type semiconducting oxide, is 5.2 eV while that of Pt is 5.65 eV with respect to the vacuum level. To experimentally confirm the Schottky barrier height between Pt and TiO2, we performed XPS analysis and measured the Schottky barrier height of 0.6 eV between Pt and Pt/TiO2 layers. When high-energy beta radiation passes through Pt and nanoporous TiO2, electron-hole pairs are produced inside the nanoporous TiO2. In particular, the holes generated in TiO2 move toward the Pt/liquid interface and then react with redox couples of water molecules, while the electrons are transported through the nanoporous TiO2 to the other electric contact due to the built-in potential at the Pt/electrolyte interface. In general, TiO2 is resistant to corrosion, but the additional layer of Pt can further protect the TiO2 layer under the harsh conditions of high pH values that are needed for water splitting. In addition, the porosity of the TiO2 leads to myriad nanoholes in the Pt film, which create localised surface plasmons that act as harmonic oscillators in response to an oscillating external electric field. Since the first report of the generation of surface plasmons on rough metal surfaces by electron illumination in 1977, many studies have examined various metal structures. Surface plasmons excited on the Pt surface can produce electron–hole pairs, with the excited electrons transiently occupying normally empty states in the Pt conduction band above the Fermi energy level. Most of the excited electrons are sufficiently energetic to enter the conduction band of TiO2.

Hi - Figure 1: Structure and mechanism of the plasmon-assisted radiolytic water splitter;

(a), Cross-sectional schematic illustration of nanoporous TiO2 prepared by anodising and thermally oxidising a thin Ti film deposited on a glass substrate. The thin Pt film is deposited on top of the TiO2nanopores using an RF sputtering system. (b), Energy level diagram of a surface-plasmon-assisted radiolytic water splitter. CB, conduction band; VB, valence band; EF, Fermi energy; eaq⁻, aqueous electron; ^·OH, hydroxyl free radical; β, beta radiation.

In contrast to photocatalytic cells, high-energy beta radiation in our device can produce free radicals in water through the loss of kinetic energy. In a meta-stable state, the free radicals are recombined into water molecules or trapped in water molecules. Thus, the free radicals produced by the radiation can be converted into electricity by a plasmon-assisted, wide band gap oxide semiconducting material using a water splitting technique at room temperature.

Hi - Structural properties of radiolytic electrode:

Scanning electron microscopy (SEM) images and X-ray diffraction (XRD) data for the nanoporous TiO2 are shown in the figure. The cross-sectional SEM image shows the existence of nanopores 100 nm in diameter and 1 μm deep with a spacing of 100 nm. The figure shows a top-viewed SEM image of a 50-nm-thick Pt film coated surface of nanoporous TiO2. After Pt deposition on nanoporous TiO2 film, the size of Pt nanoholes turns out to be approximately 10 ~ 20 nm. The density of holes is 3 ~ 5 × 10⁹ cm⁻². As shown by the XRD data in figure, after the as-deposited Ti was anodised for 5 min, the intensity of the Ti (002) peak decreased compared to that of the Ti (001) peak, indicating the presence of vertically arranged uniform nanopores along the <002> direction of the Ti. After the anodised Ti was thermally oxidised at 450°C for 2 hours, the (001) and (002) peaks of Ti disappeared, and a new peak (37.24°) corresponding to the rutile crystalline structure appeared, indicating that TiO2 has a band gap of 3.2 eV.

Hi Figure 2: Radiolytic electrode:

(a), Cross-sectional SEM image of nanoporous TiO2 on glass. (b), SEM image of Pt-coated nanoporous TiO2 viewed from the top and the inset is a SEM image of a nanohole. (c), XRD data of as-deposited Ti (black line), anodised Ti (blue line), and rutile TiO2 (red line).

Hi - Electrical properties of radiolytic cell:

Illustrations and photographs of the test setup and of the Pt/nanoporous TiO2 cathode are shown in the figure, respectively. During our experiment, gas bubbles on the PET plastic shielding film of the Sr-90/Y-90 source clearly demonstrated the occurrence of water splitting. To evaluate the radiolytic performance of the Pt/nanoporous TiO2 electrode in a 1 M KOH aqueous solution, we employed a potentiostat. We measured the current density-voltage characteristics, open circuit voltage and the current density at 0 V, −0.1 V, −0.4 V, −0.7 V, and −0.9 V for 1200 seconds each under continuous irradiation. The figure shows the current density - voltage (J-V) characteristics for the Pt/nanoporous TiO2 radiolytic electrode (red line) under irradiation. For comparison, we measured the radio current of a nanoporous TiO2 electrode (blue line) under irradiation and the dark current of Pt/nanoporous TiO2 (black line) under no irradiation. While the radio current of nanoporous TiO2 is slightly larger than the dark current of Pt/nanoporous TiO2, the radio current of Pt/nanoporous TiO2 is significantly larger than both the radio current of nanoporous TiO2 and the dark current of Pt/nanoporous TiO2. The radio current density of Pt/nanoporous TiO2 is saturated at −175.4 μA/cm² for 0 V, while the dark current density of Pt/nanoporous TiO2 and the radio current density of TiO2 are approximately −1.051 μA/cm² and −0.0719 μA/cm², respectively. At −0.9 V, the radio current density of Pt/nanoporous TiO2, the dark-current density of Pt/nanoporous TiO2, and the radio current density of TiO2 are −83.336 μA/cm², 70.31 μA/cm², and 2.85 μA/cm², respectively. These measurement data are summarized and reshaped into Table S1 to compare the performance of the irradiated devices with Pt/nanoporous TiO2 and nanoporous TiO2. The figure manifests the clear difference in output power from devices with and without the plasmonic Pt layer. The output power densities (11.59 μW/cm² at −0.1 V and 75.02 μW/cm² at −0.9 V) of the Pt/nanoporous TiO2 electrode are higher than the power densities (−0.0027 μW/cm² at −0.1 V and −2.565 μW/cm² at −0.9 V) of nanoporous TiO2. For a radioactive material activity of 15 mCi (±10%), the total number of beta particles per unit time is estimated to be 5.55 × 10⁸ s⁻¹, and the total input power density of the beta particles is 139.238 μW/cm², when the average kinetic energy of Sr-90/Y-90 is 490.96 keV. From this data, maximum energy conversion efficiency (η) of our device was approximately estimated to be 53.88% at −0.9 V using , where Prad, Pchem, and Pout are radiation power density of source (139.238 μW/cm²), chemical power density in water, and, output power density of device (75.02 μW/cm²), respectively. One possible reason for the high output power density under irradiation is that a certain level of the EHP ionisation energy of beta particles can easily excite electrons because the EHP ionisation energy is much higher than the band gap of each material while a large portion of the spectrum of solar light is below the TiO2 band gap, indicating that the TiO2 layer does not absorb sunlight well. Therefore, beta particles are a reliable energy source for electricity generation via water splitting.

Hi - Figure 3: Radio-current output at the Pt/nanoporous 
TiO2 electrode:

(a), Schematic view of the testing setup for Pt/nanoporous TiO2 under irradiation and a photograph of the Sr-90/Y-90 source with gas bubbles attached to the outer surface of the PET film. (b), Schematic diagram and photograph of the Pt/nanoporous TiO2 electrode. (c), J-V characteristics of irradiated devices with Pt/nanoporous TiO2 (red line) and nanoporous TiO2 (blue line) radiolytic electrodes and of unirradiated device with Pt/nanoporous TiO2 (black line) in a dark room. (d), Power densities of irradiated devices with Pt/nanoporous TiO2 (red bar) and nanoporous TiO2 (blue bar). The area of the electrode is 1 cm².

Hi - Energy absorption of electron beam in the radiolytic 

cell using numerical simulation:

To study the mechanism of the enhanced power conversion of beta radiation, we calculated the energy absorbed in an aqueous solution using Monte Carlo (MC) simulations. The number of electrons utilised in this simulation was 10,000, and the kinetic energy of the electron beam was 546 keV. A beta particle is an electron, e⁻, or a positron, e⁺, that is generated when the neutron to proton ratio in the nucleus is too large, making the nucleus unstable. In this simulation, the presence of secondary electrons generated by primary electrons was ignored, and the electron beam was defined by a Gaussian distribution. The energy absorbed by the TiO2 film was calculated to be approximately 0.25% of the total energy of the electron beam. In the middle of the water, the absorbed energy was approximately 55.57%. Note that the incident beta radiation can be scattered and reflected by our nanoporous structure, indicating that more energy will be absorbed by Pt/nanoporous TiO2 and water than expected in this simulation. Beta radiation can create vacancies in solids by primary knock-on atoms (PKA). For rutile TiO2, the threshold displacement energy is about 47 eV. A required incident kinetic energy level of beta radiation for the vacancy production can be estimated from the displacement energy equation, Tm = 2(E + 2mc²)E/Mc², where E is kinetic energy of beta radiation and c is speed of light. m and M are masses of electron and target atom, respectively.The Figure shows the relationship between the incident kinetic energy of beta radiation and the threshold displacement energy. Under beta radiation, the threshold displacement energy of 47 eV is equivalent to the incident kinetic energy of 271 keV for oxygen and 633.5 keV for titanium as shown in figure. We also found from MC simulations that the water can absorb beta radiation of 356 keV. Because the PKA damage in TiO2 occurs from the kinetic energy over 271 keV as shown in the figure, the performance degradation of our radiolytic cell might begin with the kinetic energy over 627 keV. Although beta radiation from Sr-90/Y-90 includes higher energy beta particles than 627 keV as shown in the figure, our radiolytic cell didn't show any performance degradation for about 6 hours. Moreover, water can absorb 72.02% of the total kinetic energy in emission spectrum of Sr-90/Y-90. To determine the total kinetic energy passing through Pt/nanoporous TiO2, we considered the directional loss of radiation source. As shown in the figure, the directional loss of our radiolytic cell is estimated to be approximately 54.88% and the amount of kinetic energy higher than 627 keV is only 12.62% of the total kinetic energy of beta radiation, indicating that performance degradation of our radiolytic cell may not be serious. Here, incident high-energy beta particles can excite electrons in the semiconductor via their energy loss, which is defined as the electron-hole pair (EHP) ionisation energy given by W± ≈ 2.8Eg + Eph, where Eg and Eph are the band gap and phonon energies (0.5 ≤ Eph ≤ 1 eV), respectively. For TiO2, W± is approximately 9.46 eV. Because the high EHP ionisation energy is sufficient for tunnelling through a low Schottky barrier at the TiO2/liquid interface, the radio current of nanoporous TiO2 is lower than the radio current of Pt/nanoporous TiO2, as shown in the figure. When beta particles pass through the TiO2 layer (1 μm), the number of generated EHPs is estimated to be approximately 144 per single beta particle, that is, the deposition power is estimated to be 0.12 μW/cm². Although most of the EHPs generated within the depletion region are separated due to the built-in potential of the thin TiO2 layer, the measured output power density was much less than the expected values of 75.02 μW/cm² at −0.9 V. This result indicates that the EHPs generated in TiO2via beta radiation are not sufficient to produce the total output power density measured in the experiment.

Hi - Figure 4: MC simulation of the electron beam in the radiochemical cell:

(a), Absorbed energy distribution of the electron beam in the PET (20 μm)/water (1 mm)/Pt (50 nm)/TiO2(1 μm)/glass (1 mm) structure. (b), Cross-sectional view of the absorbed energy intensity at the centre of the electron irradiation.

Hi - Generation and behaviour of free radicals under beta radiation:

To understand the highly enhanced output power, it is necessary to understand the details of water radiolysis. High-energy electrons passing through an aqueous solution can ionise or excite water molecules, forming a number of transition species and stable products, as shown by the equation , ^·OH, H^·, HO2^·, H3O⁺, OH⁻, H2O2, H2. High levels of these products are formed by the absorption of 100 eV in the medium. The generated radicals are powerful redox reagents, i.e., eaq⁻ is a strong reducing agent, H^· is an equally strong reducing and oxidising agent, and ^·OH is a powerful oxidising agent. In water at high pH, eaq⁻ and ^·OH are produced in the largest quantities by the beta radiation. The standard potentials of eaq⁻ and ^·OH are E⁰ (H2O/eaq⁻) = −2.9 VNHE and E⁰ (^·OH/H2O) = +2.7 VNHE, respectively. These two species (eaq⁻ and ^·OH) react with water molecules during water radiolysis and then remain in the aqueous solution. They can then no longer react with each other or with surrounding water molecules. Once these two species (eaq⁻and ^·OH) are solvated in an aqueous solution, they can be surrounded by water molecules in a meta-stable state for a few μs. It is well known that water has a very large dielectric constant and consists of polar molecules, which prevent the electrostatic attraction between positive and negative charges and maintain the separated state of charges surrounded by oppositely charged ends of water dipoles. During the long lifetime of solvated electrons, beta radiation will continuously increase the number of solvated electrons in the water until they finally move to the surface of the water, where they are emitted as thermal energy. The floated electrons form the negatively charged surface of water. Theoretically, water has lower standard potential (E⁰ (H2O/O2) = +0.82 VNHEand E⁰ (H2O/H2) = −0.41 VNHE) than free radicals, indicating that electrochemical energy of water is lower than that of free radicals. It was also reported that high electrochemical energy of solvated electrons (eaq⁻) can enable difficult chemical reactions to happen. Moreover, the presence of an external electric field or electromagnetic field can release the solvated electrons from their confined environment of surrounding molecules. This is because eaq⁻ in water has very small diffusion efficiency (4.8 × 10⁻⁵ cm²/s) and electron mobility (1.84 × 10⁻³ cm²/V·s). Solvated electrons in water also need to get over the potential barrier of 0.2 ~ 0.5 eV set by the surrounding rigid water molecule network. Moreover, because water is located between both Pt electrodes (plasmonic layer and counter electrode), if same electrochemical reactions occur on both Pt surfaces, simply no current flow is expected.

FDTD simulations of Pt/nanoporous TiO2 on glass under an e-beam irradiation of 546 keV and optical measurement

One available external electric field in our device is the localised electric fields from the surface plasmons of the Pt nanoholes. To generate surface plasmons on the Pt/nanoporous TiO2 radiolytic electrode, we performed 3D-FDTD (finite-difference time-domain) numerical simulations using a commercially available FDTD code for simulating electron irradiation. In FDTD, the macroscopic Maxwell equations are solved in discretised space and time to follow the response of a material to an applied electric field. For a numerical investigation of the beta radiation-excited photon emission in Pt/nanoporous TiO2, the electron beam can be modelled as a line current density source represented by  , where e is the electronic charge, vis the electron velocity, (x0, y0) represents the position of the focused electron beam, z is the direction of the electron velocity, and ûz is the unit vector along the z direction. In the simulation, the current density was modelled as a series of dipoles with a temporal phase delay (z/v) related to the electron velocity, v (in this simulation, v = 0.875c, corresponding to the beta particle's kinetic energy of 546 keV used in the experiment, and c is the velocity of light in free space). We conducted our simulations for three different points denoted 1–3 in the middle of a pore, at the side wall of a pore, and between two pores, as depicted in the figure.

Hi - Figure 5: FDTD simulations of Pt/nanoporous TiO2 on glass under an e-beam irradiation of 546 keV and optical measurement.

(a), Cross-sectional view and top view for different e-beam positions marked as 1–3. In this simulation, d, s, t1, and t2 are 10 nm, 200 nm, 50 nm, and 45 nm, respectively. (b), Emission spectra of the Pt/nanoporous TiO2 surfaces at positions 1–3. Arrows indicate the highest peak positions. Mark 4 shows the reflection of Pt/nanoporous TiO2 using an UV-VIS spectrometer. The same coloured dots indicate corresponding peaks of each spectrum. (c–d), Top and cross-sectional views of the near-field intensity distributions on Pt/nanoporous TiO2 at the top level of Pt nanohole at mark 1 for 290 nm. (e–f), Top and cross-sectional views of the near-field intensity distributions on Pt/nanoporous TiO2 at the top level of Pt nanohole at mark 2 for 287 nm. (g–h), Top and cross-sectional views of the near-field intensity distributions on Pt/nanoporous TiO2 at the top level of Pt nanohole at mark 3 for 377 nm. The field intensity is shown on a log scale, [E]²/[E0]², where E and E0 are the generated and minimum electric field intensities, respectively.
To simulate the near-field electric intensities and emission spectra at the different positions, the induced electric field distributions were calculated by [E]²/[E0]², where E and E0 are the generated and minimum electric field intensities, respectively, emitted normal and parallel to the Pt surface in the wavelength range of 200 to 700 nm. We investigated the near-field intensity distributions on Pt/nanoporous TiO2 at the different positions under focused electron irradiation using FDTD simulations. As shown in Fig. 5b, the highest emitted spectral peaks were calculated to occur at wavelengths of 293 nm, 517 nm, and 376 nm when the electron irradiation is focused near positions 1, 2, and 3, respectively. These results indicate that the strongest surface plasmon energy (4.23 eV) and field intensity are generated when the nanohole is irradiated. Such strong surface plasmons have been observed in Pt nanostructures at similar energy levels due to an interband transition of the particles. The diffraction pattern is also shown for position 3 on periodic Pt/nanoporous TiO2. To confirm the surface plasmons, we measured the reflectance of Pt/nanoporous TiO2 structures using an UV-VIS spectrometer. As shown in Fig. 5b, marks 1–3 are the calculated emission spectra of Pt/nanoporous TiO2 in water, while mark 4 is the measured reflectance of Pt/nanoporous TiO2 in air. The reflection peaks (colour dots) of mark 4 were found at the similar positions with respect to the simulated emission peaks shown at marks 1–3. The strongest reflection peak (purple arrow) of Pt/nanoporous TiO2 is shown at 245 nm (5.06 eV) by plasmon resonant coupling in air/Pt nanoholes. To understand the surface plasmon phenomena between two materials, we have to solve Maxwell's equation for the electromagnetic wave at the interface between two materials, which has relative dielectric functions ε1 ( = ε′1 + iε″1 = (n1² − κ1²) + i(2n1κ1)) and ε2 ( = ε′2 + iε″2 = (n2² − κ2²) + i(2n2κ2)) with the appropriated continuity relationship. Real and imaginary parts of the dielectric function are presented. The nj and κj are refractive index and extinction coefficient, respectively, and j is 1 or 2. By boundary conditions, the dispersion relation for a wave propagating on the surface is  , where k ( = k′ + ik″), ω and c are the wave number and the frequency of the wave, the speed of light, respectively. For k′ not to be purely imaginary, ε′1 = (n1² − κ1²) < 0 and |ε′1| > ε′2 = (n2² − κ2²). Based on this relationship, we have plotted a graph shown in Fig. S7. Since the surface plasmon energy occurs around |ε′1| ≈ ε′2, the surface plasmon wavelengths can be found from crossing points on the Pt line (black line). Compared to the water/Pt (green/black) interface, the air/Pt (blue/black) interface shows the surface plasmon phenomena at a slightly shorter wavelength. These wavelengths at the crossing points (red and green dots) of water/Pt and air/Pt in Fig. S7 are very close to the wavelengths at the strongest reflection peaks (red and green dots) as marked 1 and 4 in Figure 5b. Furthermore, the surface plasmon energy at the Pt/TiO2 interface is consistent with a dip (blue dot) near 450 nm. Therefore, matched data from the emission peak shown at mark 4 in Fig. 5b and the green dot shown in Fig. S7 indicate evidence of plasmon resonant coupling in air/Pt nanoholes under e-beam irradiation. There are only very small amounts of variation among the two layer calculation data (Fig. S7), the multi layer simulation results (Fig. 5b-1 ~ 3) and the experimental data (Fig. 5b-4). In addition, as shown in the electron profiles in Figs. 5c–h, the highest electric field intensities can trace electron irradiation paths (electric dipoles), and simultaneously, the electric field intensities in the Pt/nanoporous TiO2 structures are also strengthened near the electron irradiation paths by surface plasmons generated at the Pt nanoholes.

Hi - Discussion:

Electrons and holes that migrate to the surface of metal electrodes can reduce and oxidize the reactants adsorbed on the metal surfaces, respectively. The reduction (Red) and oxidation (Ox) reactions can produce the reduction current and oxidation current as shown in the J-V measurement data in Fig. 3c. The oxidation current density (lower red curve) is less than reduction current (upper red curve) at 0 V under irradiation, meaning that the reaction Red ⇒ Ox + ne⁻ is dominant on Pt/nanoporous TiO2 and available electrons are provided continuously, whereas the current density data (upper and lower black lines) of unirradiated devices seem not much different. When the strongly localised electric field oscillates across the Pt surface, as illustrated in Figs. 5c–h, the displacement of the electron density in the Pt surface by the electric field oscillation generates a Coulombic attraction force that can interact with environmental molecular ions, meaning that the eaq⁻ and ^·OH ions surrounded by water molecules can escape and attach to the Pt surface via localised surface plasmons. However, when the localised surface plasmon energy is less than the energy barrier of eaq⁻ and ^·OH, they cannot coherently oscillate or escape from their meta-stable state. With respect to the vacuum level, the work functions of eaq⁻ and ^·OH were calculated to be 1.6 eV and 7.2 eV, respectively, at pH 0. From the FDTD simulations, we obtained surface plasmon energy of 4.23 eV, which is 1.42 eV from the vacuum level and is higher than the energy level of eaq⁻, enabling electrons to escape from their meta-stable state and the escaped electrons to generate surface plasmons on the metal surface. In addition, the presence of excited electrons indicates that excited holes with the same amount of energy (10.64 eV with respect to the vacuum level) exist. These excited holes can interact with ^·OH on the surface of Pt. The same phenomenon is responsible for Förster resonant energy transfer (FRET), in which an excited donor transfers energy to an acceptor group through a non-radiative process. In fact, the Schottky junction of Pt/TiO2 creates a space-charge region in the n-type TiO2 layer because the electrons diffuse from the TiO2 side to the Pt side whereas the holes move in the reverse direction. In the equilibrium state, an equal amount of electrons in Pt is trapped at the Pt/TiO2 interface and builds up an internal electric field (0.45 eV) from the TiO2 side toward the Pt side, preventing further movement of carriers. When surface plasmons are generated on Pt surface by beta radiation, electrons in Pt are pushed towards TiO2 by the electric field created from surface plasmons, which is higher than the internal electric field, and holes move simultaneously towards the Pt/water surface interface. Accumulated holes can attract donors like negatively charged ions or radicals. Thus, the strong electric field enhancement can significantly increase the number of accumulated holes at the Pt/water interface and create a large internal potential difference. With the energy higher than the potential barrier (0.2 ~ 0.5 eV) of surrounding water molecules, solvated electrons (eaq⁻) can be attracted toward the Pt surface rapidly in water. Moreover, surface plasmons have a resonance frequency of a few hundred of GHz in visible wavelength. This means that strong Coulombic attraction force oscillates very fast to attract eaq⁻ in water. When the distance between the TiO2and Pt counter electrode is 5 cm, the electric field is approximately 0.09 V/cm and the speed of electrons in water reaches 1.6256 × 10⁻⁴ cm/s. If eaq⁻ in water is 1 mm away from TiO2, it can move to the TiO2 surface in 603 s and most solvated electrons will not arrive quickly at the TiO2electrode. Thus, as shown in Fig. S2, a slowly saturated curve of open circuit voltage is observed on TiO2 electrode under beta radiation, while the Pt/TiO2 electrode has a very fast saturated curve. The electric field of the TiO2 electrode is much weaker than that of the Pt/TiO2 electrode producing the surface plasmon effect, and the difference in electric field intensity may affect the collection ofeaq⁻ in water. Once eaq⁻ is arrived at the electrode surface, eaq⁻ is injected without any energy loss because the electrochemical energy is higher than the conduction band edge (−0.1 ~ −0.2 VNHE) of TiO2.

In principle, photovoltaic devices, such as dye-sensitised solar cells and photochemical cells, use the similar mechanism, but sunlight produces very few free radicals because it is composed of photon energies that lie primarily in the visible range (380 nm–780 nm). Differently, beta radiation can produce many free radicals through the loss of kinetic energy in water. Then, the generation of localised surface plasmons on the Pt surface by beta radiation can enhance the chemical reactions involving free radicals produced by beta radiation in water. The reflection peak of Pt/nanoporous TiO2 at 5.04 eV, and the similarity between the simulated emission spectra and measured reflection spectrum show that the surface plasmon resonance occurs at higher energy than the band gap energy of TiO2, indicating resonant energy transfer between TiO2 and surface plasmons. Because the increased population of hot electrons generated by surface plasmons decreases the thickness of the Pt/TiO2 junction and increases its junction electric field, the narrow junction enables carriers obtained from free radicals to efficiently move toward the contact metals without carrier relaxation in the thin film. We confirmed that significantly more power from the device with the plasmonic Pt layer was produced than that from the device without the plasmonic Pt layer. As shown in Fig. S12, increased surface plasmon energy can effectively transport hot carriers generated on a Pt surface. Therefore, we can conclude that the high power density obtained from our radiolytic cell may be attributed to the conversion of continuously generated free radicals with large electrochemical energy into electricity by the surface plasmon energy generated at the Pt surface. This finding reveals new mechanisms for power generation in radiolytic chemical cells. Our unique approach further paves the way for producing chemical cells with higher power density.

Hi - Methods:

Hi - Sample preparation:

A 2-μm-thick titanium film was deposited on a glass substrate using an RF sputtering system, and an area of 1 cm² was patterned for an electrode. The substrate was cleaned with a standard solvent cleaning process, dried under a flow of N2 gas, and immediately anodised in a 0.01 wt% HF aqueous solution under an applied voltage of 40 V for 5 min. Immediately after cleaning and drying the anodised Ti films, the substrate was annealed in a convection oven at 450°C for 2 hours. A 50-nm-thick Pt film was deposited on the thermally oxidised Ti films using an RF sputtering system. A copper wire was connected to the electrode of each sample and covered with epoxy to electrically isolate the electrolyte.

Hi Structural and optical properties:

Scanning electron microscopy (SEM) was performed using an FEI Quanta 600 FEG extended vacuum scanning electron microscope with an accelerating voltage of 10 kV and an energy dispersive spectrometer (Noran System Six). X-ray diffraction (XRD) analysis was conducted using a Rigaku Miniflex 600 X-ray diffractometer with Cu Kα radiation. The reflection spectrum was measured using a Perkin-Elmer lambda 25 UV-VIS spectrometer and variable-angle reflectance accessory.

Hi - Electrical properties:

Consecutive J-V measurements were collected from 1.0 V to −1.5 V with respect to Ag/AgCl reference electrodes in a three-electrode system at a fixed scan rate of 0.05 V/s. The electrolyte solution was 1 M KOH (Sigma Aldrich, 99%). A radioisotope source (Sr-90/Y-90, 15 mCi) sealed in stainless steel was chosen for our experiment. The distance between the electrode and the radiation source required to maintain a constant activity of 15 mCi at the surface of the device was determined to be approximately 1 mm. A potentiostat (DY2322, Digi-Ivy) was connected to the three (reference, counter, and working) electrodes for data collection. All experiments were performed in a dark room to eliminate the effects of a photocurrent. In addition, to ensure that the reaction only involved diffused radicals, the solution was not agitated.

Hi - FDTD simulation:

We used Pt (50 nm)/nanoporous TiO2 (1 μm) composed of a periodic array of nanoholes with a diameter of 10 nm and a depth of 505 nm. The electron beam was modelled as a series of closely spaced dipoles with a temporal phase delay defined by the velocity of the electron beam. In the absence of a structure, an electron beam moving at a constant velocity does not generate any radiation. The material properties used in the calculation are based on the dispersion data given in refs. 64 and 65. The detailed electron irradiation profiles at the different positions at the bottom level of the nanoholes in the supplementary information show the strong influence of the Pt/nanoporous TiO2 structures on the scattering direction.

Hi References & Supplementry Content:

- Click the following link here to download references.

- Click the following link here to download the supplementary information. 

- Click the following numbered links for supplementary movies; mov.2, mov.3, mov.4, mov.5, mov.6 & mov.7.